file: Strategy.txt version: 27Nov98 contents: CSU sampling strategies Measurements of ice nucleating aerosol particles were obtained during May 1998 NCAR C-130 research flights as part of NASA's FIRE3 Arctic Cloud Experiment. This document outlines the sampling strategies and procedures for these measurements. DEFINITIONS CFD = Continuous Flow Diffusion chamber SSw = CFD sample liquid water vapor supersaturation (%) TEM = Transmission Electron Microscope IN = Ice Nucleating aerosol particle = IFN (Ice Forming Nuclei) CFD Sampling Conditions The CFD samples at one set of temperature and supersaturation (T,SS) conditions, selected by the operator. The CSU sampling strategy was to choose (T,SS) conditions to be consistent with local clouds and cloud- forming regions. Over a period of time, samples were taken both above and below water saturation, with the maximum supersaturation typically about +5%, and the minimum typically -5%. Occasionally, samples were made at very high SSw (>10%) for a few minutes. The general strategy was: Maintain constant (T,SS) conditions: a) During vertical profiles b) During impactor samples Vary conditions to get (T,SS) spectrum: a) When flying at approximately constant altitude in a relatively homogeneous region, for example during ferry flights between Fairbanks and the SHEBA ice camp. Try to span a 10øC range of temperature and +/-5% in supersaturation. b) During some of the IN membrane filter samples. CFD Impactor Samples Samples of ice crystals which nucleated and grew in the CFD were impacted onto electron microscope grids. The strategy was to collect as many as practicable with the CFD steady at one (T,SS) setting. The number of crystals was monitored during sampling (based on optical counts), with the goal of collecting several hundred particles on each grid. Typical exposure time was 30 minutes. PIXE TEM Grid Impactor Samples The PIXE impactor is an inertial impactor for size-sorted samples of total aerosol larger than ~60nm. The CSU TEM grids are copper mesh with a formvar film and a light carbon coating. PIXE samples were taken directly from the aerosol duct, not through the CFD flow distribution panel. Flow was monitored with a rotameter downstream of the PIXE. Samples were obtained simultaneous with CFD impaction samples. Typical sample durations will be 10-20 minutes. Only use stages 1, L2 and L1 were used, with a TEM grid at L1 (0.06um) or on stages L2 and L1. Samples were changed in flight by storing exposed and unexposed disks in covered petri dishes. TEM grids were loaded and unloaded at the hotel room. Blank samples were also taken using the same handling procedures as exposed grids but no airflow. IN Membrane Filters Hydrophobic Nuclepore filters with 0.2um pore size were used. Exposed filters are stored and processed at CSU after the project. Filter samples were taken directly from the aerosol duct, not through the CFD flow distribution panel. Pairs of filters were collected simultaneously with CFD measurements, with one filter at 10 LPM, and the other at 2 LPM. Flow was measured using rotameters with valves located just downstream of the filters. Sample duration was 0.5 to 1 hour. It was not necessary to maintain CFD (T,SS) during filter samples since (T,SS) spectra can be derived from the filters during processing. Filters were in sealed filter holders except when being loaded or unloaded at the hotel room. Exposed filters were transfered to covered plastic petri dishes, labelled to identify the sample. Blank samples were taken, using the same handling procedures as exposed filters but no airflow.